How can I derive the energy of an electron using the electron in a box model?

The electron in a box model uses the idea that the energy of the electron and that of a standing wave in a box are analogous. So using your knowledge of standing waves you can derive an equation for the electrons energy.

The equation you need to derive is KE = (n2h2)/(8mL2)

It looks a little daunting and is not something I would memorise. Thankfully the derivation just requires 3 main steps and 3 main equations.

Treat the electron in a box as you would treat a standing wave on a string length L. The boundary conditions are that the wave has nodes at either end of the string. If you start drawing out the possible wavelengths on a string length L you will start to see a relationship emerging between the number of anti-nodes, n, and the wavelength, λ. Thus the allowed wavelengths are λ = 2L / n where n = 1, 2, 3, ...

Now that we have this relation we can use our equations from quantum physics, look for one that might includes λ, in this case λ = h / p.

Now substitue p = mv we have λ = 2L / n  = h / (mv). Which rearranges to v = (hn) / (2Lm). So now we have an equation for the velocity of the electron in terms of L.

Remember we needed to find an expression for the energy, but there is the equation KE = mv/ 2. So by substitution:

KE = (n2h2)/(8mL2)

This equation can model the energies of an electron according to it's energy level in the atom. So the n in the equation represents its energy level, the h is Planck's constant, m is the mass of the electron and L is the the length of the box or the space to which the electron is confined.

LC
Answered by Lucile C. Physics tutor

13241 Views

See similar Physics IB tutors

Related Physics IB answers

All answers ▸

1 dm^3 of water steam at 200 degrees C, 10 bar enters a compressor. When it leaves, its temperature is 400 deg. C and volume 0.5 dm^3. Calculate the final pressure of steam. Critically discuss the assumptions you made in your calculations.


What is energy


What is the difference between EMF and Voltage?


Why is centripetal acceleration directed inwards to the centre of the circle during centripetal motion? If I’m in a car while it’s cornering, I seem to be pushed outwards away from the centre, not inwards.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

© MyTutorWeb Ltd 2013–2025

Terms & Conditions|Privacy Policy
Cookie Preferences