Why is 2-trichloroethanoic acid such a strong acid?

Cl is very electronegative, which makes it electron withdrawing. This means the three Cl substituents pull electrons from the O-H bond. This causes further polarisation of the O-H bond, which means there is a strong tendency for the H+ to be lost from the molecule. Furthermore, the Cl groups then can pull electron density from the negative O-, which will stabilise the ion. I.e. the negative charge experiences some delocalisation. This means there is a decreased likelihood the ion will just reattach to a lost proton (H+), causing there to be a large concentration of H+ within the solution. This gives the lower pH.

LS

Related Chemistry A Level answers

All answers ▸

Nitrous acid, HNO2, is a weak Bronsted-Lowry acid with a Ka value of 4.43x10-4 mol dm-3. Calculate the pH of 0.375 mol dm-3 of HNO2.


Suggest why Phenol is more reactive than Benzene in Electrophillic Substitution


State the meaning of the term first ionisation energy


For the following reaction, you obtained 7.2 g of sodium sulfate, starting from 10 g of sulfuric acid. Sodium hydroxide is in excess. What is the % yield? H2SO4 + 2NaOH → Na2SO4 + 2H2O