Why is 2-trichloroethanoic acid such a strong acid?

Cl is very electronegative, which makes it electron withdrawing. This means the three Cl substituents pull electrons from the O-H bond. This causes further polarisation of the O-H bond, which means there is a strong tendency for the H+ to be lost from the molecule. Furthermore, the Cl groups then can pull electron density from the negative O-, which will stabilise the ion. I.e. the negative charge experiences some delocalisation. This means there is a decreased likelihood the ion will just reattach to a lost proton (H+), causing there to be a large concentration of H+ within the solution. This gives the lower pH.

LS

Related Chemistry A Level answers

All answers ▸

Explain how the electron pair repulsion theory can be used to deduce the shape of, and the bond angle in, NH3.


What are covalent bonds?


Predict whether the lattice energy of magnesium oxide, MgO, is more or less exothermic than the lattice energy of magnesium sulfide, MgS. Justify your answer in terms of the sizes and the charges of the ions involved.


Why is benzene more stable than the theoretical model cyclohexa-1,3,5-triene?