Why is 2-trichloroethanoic acid such a strong acid?

Cl is very electronegative, which makes it electron withdrawing. This means the three Cl substituents pull electrons from the O-H bond. This causes further polarisation of the O-H bond, which means there is a strong tendency for the H+ to be lost from the molecule. Furthermore, the Cl groups then can pull electron density from the negative O-, which will stabilise the ion. I.e. the negative charge experiences some delocalisation. This means there is a decreased likelihood the ion will just reattach to a lost proton (H+), causing there to be a large concentration of H+ within the solution. This gives the lower pH.

LS

Related Chemistry A Level answers

All answers ▸

A sample of nitrogen gas is heated to 100°C, at a pressure of 10kPa and volume of 0.2m^3. How many moles of gas are present?


How do you calculate the pH of a weak acid?


How are amino acids involved in condensation and hydrolysis reactions?


What is the difference of SN1 and an SN2 mechanism?