Why is 2-trichloroethanoic acid such a strong acid?

Cl is very electronegative, which makes it electron withdrawing. This means the three Cl substituents pull electrons from the O-H bond. This causes further polarisation of the O-H bond, which means there is a strong tendency for the H+ to be lost from the molecule. Furthermore, the Cl groups then can pull electron density from the negative O-, which will stabilise the ion. I.e. the negative charge experiences some delocalisation. This means there is a decreased likelihood the ion will just reattach to a lost proton (H+), causing there to be a large concentration of H+ within the solution. This gives the lower pH.

LS

Related Chemistry A Level answers

All answers ▸

What is Mass Spectrometry?


What's added to Ethanoyl Chloride to make Methyl Ethanoate? Draw out the mechanism for this reaction. Why is this preferred to esterification?


In organic chemistry, how can functional groups be easily identified and how can I memorise organic mechanisms?


How do I systematically name alkanes?