Explain why the enthalpy of lattice dissociation of potassium oxide is less endothermic than that of sodium oxide.

Lattice dissociation enthalpy is the enthalpy change when one mole of a gaseous ionic lattice dissociates into isolated gaseous ions. The process is endothermic because energy is required to overcome the electrostatic attraction between oppositely charged ions. Sodium and potassium ions both have the same charge (+1) but the potassium ion is larger so the electrostatic forces of attraction are weaker in potassium oxide. Hence less energy is required to separate the ions making the enthalpy of lattice dissociation less endothermic.

LJ

Related Chemistry A Level answers

All answers ▸

What is the trend in electronegativity of group 7?


How do you decide what the sign of the enthalpy change should be?


A chemist mixes together 0.450 mol N2 with 0.450 mol H2 in a sealed container. The mixture is heated and allowed to reach equilibrium. At equilibrium, the mixture contains 0.400 mol N2 and the total pressure is 500 kPa. Calculate Kp.


What is the definition of structural isomerism and what are the different types?