Write a balanced equation for the reaction between NaOH and sulfuric acid. A conical flask contains 25cm^3 of 0.124M NaOH, a burette contains 0.0625M sulfuric acid. Find the minimum amount of acid required to completely react with the NaOH in the flask.

first, consider balanced equation: consider reaction occuring: NaOH + H2SO4 --> Na2SO4 + H2O (neutralisation) ions present in each reactant: NaOH: Na+, OH-  H2SO4: 2H+, SO42- - SO42- requires 2 Na+ ions to form a neutral compound - the 2 H+ ions each require 1 OH- to form water answer: 2NaOH + H2SO4 --> Na2SO4 + 2H2O now consider calculation: how many moles of NaOH are there in the flask? recall: number of moles = volume (in dm3) x concentration (in moldm-3) first, convert 25 cm3 into dm3, by dividing by 1000: 25 cm3 = 25 / 1000 dm3 = 0.025 dm3 now, plug numbers into equation: number of moles of NaOH = 0.025 dm3 x 0.124 moldm-3 = 0.0031 mol what is the minimum number of moles of H2SO4 required to react completely with the NaOH? from balanced equation (see above), NaOH : H2SO4 = 2 : 1 (stoichiometry of reaction) - this means that 2 molecules of NaOH are required to react with 1 molecule of H2SO4 so, number of moles of H2SO4 required = 0.0031 mol / 2 = 0.00155 mol what is the minimum volume of H2SO4 required? recall: number of moles = volume (in dm3) x concentration (in moldm-3) rearrange equation to give: volume (in dm3) = number of moles / concentration (in moldm-3) so, minimum volume of H2SO4 required = 0.00155 mol / 6.25 x 10-2 moldm-3 = 0.0248 dm3 = 24.8 cm3 answer: 24.8 cm3

HM

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