Why do the atomic radii of the elements decrease across Period 3 from sodium to chlorine?

The atomic radius of an atom is the distance from the atom's nucleus to its outermost electron. Moving across Period 3, the number of protons in the nucleus increases - for example sodium has 11 protons, and chlorine has 17 protons. Nuclear charge increases across the period, therefore the attraction between the positively charged nucleus and negatively charged electrons increases, so the atomic radii decreases. The number of electrons also increases across a period, but as each extra electron enters the same principal energy level, there is relatively little extra shielding.

AT
Answered by Amy T. Chemistry tutor

31776 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

(i) What property does Magnesium Oxide have that makes it useful to create heat-resistant bricks to line furnaces? (ii) Explain why H2S exists as a gas and H2O exists as a liquid (at r.t.p).


Why does phenol readily undergo electrophilic substitution but benzene does not without the aid of a catalyst?


Comparing aluminium and magnesium, which has a lower first ionisation energy? Explain.


Elemental analysis of a carbohydrate X showed the sample contained 48.7 % carbon and 8.1 % hydrogen by mass. Find the empirical formula of X.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning