Describe the products of the following Friedl-Crafts substitution and explain the role of the AlCl3 in the reaction: C6H6 + CH3C(O)Cl + AlCl3 = ?

C6H6 + CH3C(O)Cl = C6H5C(O)CH3 + HCl

This is an example of an electrophilic aromatic substitution reaction, with the product being a ketone. The AlCl3 serves as a catalyst, converting the acyl chloride into a stronger electrophile to encourage attack by the relatively weakly nucleophilic benzene.

AlCl3 is electron-deficient so can act as a Lewis acid and accept a pair of electrons from the acyl chloride.

CH3C(O)Cl + AlCl3 = CH3C+(O) + Al-Cl4 

The CH3C+(O) now has a stronger delta + than the acyl chloride, activating it towards electrophilic substitution by the benzene.

The AlCl3 regenerated at the end of the reaction.

TH
Answered by Thomas H. Chemistry tutor

12389 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Why dose sodium oxide have a high melting point?


What is electronegativity?


Describe how you would differentiate a sample of butanal and butan-2-one.


Chlorobenzene can be produced by electrophilic substitution of benzene? Draw the mechanism for this?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning