Why do the atomic radii of the elements decrease across a period on the periodic table.

It may seem counterintuative that as the elemets' atomic numbers increase their atomic radii decrease. This is due to the increased electrostatic attraction (coulombic interaction) between nucleus and valence electrons. As long as elements are all in the same period then all thier valence electrons are in the same energy level, so there is no increase in the atomic radius due to fillig a new outer shell. This means the dominant effect is simple the electrostatic interaction. As the atomic number increases so does the interaction force, hence the atomic radius decreases.

DH
Answered by Daniel H. Chemistry tutor

3805 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Describe how you would distinguish between separate samples of the two 2 0 4 stereoisomers of CH3CH2CH2CH2CH(OH)CN [2 marks]


Without a catalyst, an alkene will react with bromine while benzene will not. Why is this?


Give the reagents required for the nitration of toluene (methylbenzene) to 2,4,6-trinitrotoluene and provide a mechanism.


How do I write the full equation of a cell from two half cells? (basic, with matching electron counts and no water/acid)


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning