Why do the atomic radii of the elements decrease across a period on the periodic table.

It may seem counterintuative that as the elemets' atomic numbers increase their atomic radii decrease. This is due to the increased electrostatic attraction (coulombic interaction) between nucleus and valence electrons. As long as elements are all in the same period then all thier valence electrons are in the same energy level, so there is no increase in the atomic radius due to fillig a new outer shell. This means the dominant effect is simple the electrostatic interaction. As the atomic number increases so does the interaction force, hence the atomic radius decreases.

DH
Answered by Daniel H. Chemistry tutor

3840 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

What are the three pieces of evidence that disprove the Kekulé model of Benzene?


Explain why the product of nucleophilic addition of a cyanide ion to the ketone CH3COCH2CH3 shows no optical activity


Explain why the second ionisation energy of boron is higher than the first ionisation energy of boron.


Explain why the first ionisation energy of Al is less than that of Mg?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning