Calculate the pH change when water is added to 25.0 ml of 0.250M NaOH to form a 1.00l solution.

The initial [-OH] is 0.250M since NaOH releases 1 mole of -OH per mole of base. Using Kw=[H+][-OH], [H+]=(110-14)/0.250=410-14M (note remember units). Hence the initial pH=-log(410-14)=13.4 (note 3 significant figures since same s.f. as values in question). The diluted [-OH] is 0.250(25/1000)=6.2510-3M (dilution factor, remember units). Using Kw=[H+][-OH], [H+]=(110-14)/(6.2510-3)=1.610-12M. Therefore the new pH=-log(1.6*10-12)=11.80. Hence the pH change is 11.80-13.40=-1.60, so a decrease of 1.60pH units. I would write down the question on the whiteboard, and allow the student to work through it, giving guidance and helpful suggestions when they struggled/became stuck - but not simply telling them the answers because it is most beneficial for the student to think through the question for themselves.

MS
Answered by Milind S. Chemistry tutor

16772 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

How do I know if an enthalpy change should be positive or negative?


Describe a two step reaction route that can convert 1-Butene (CH2CHCH2CH3) into a compound that is more soluble in water. Use mechanisms to aid your answer (HINT: one of the steps involves nucleophilic substitution)


What is the difference between complete and incomplete combustion of a hydrocarbon?


Propane and Chlorine react in the presence of UV light to give 2-chloropropane and HCl. Estimate the enthalpy change of this reaction using the following bond enthaplies (KJ/mol) : C-H=+413, Cl-Cl=+243, C-Cl=+346 and H-Cl=+432.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning