Giving the electronic configurations for each element, predict the trend in 1st ionisation energies going across period 2 from Lithium to Neon.

First start by giving the definition of first ionisation energy - the energy required to remove one mole of electrons from one mole of gaseous atoms to produce one mole of gaseous ions each with a +1 charge, so we're removing the outermost electron from each of our atoms.

Then have a go at writing down the electronic configurations of each element, it will help to have your periodic table in front of you for this, it is also useful to split the 2p sub-shell into its individual orbitals i.e px, py and pz as well.
Li - 1s22s1
Be - 1s22s2
B - 1s22s2 2px1
C - 1s22s2 2px12py1
N - 1s22s2 2px12py12pz1
O - 1s22s2 2px22py12pz1
F - 1s22s2 2px22py22pz1
Ne - 1s22s2 2px22py22pz2

We expect to see that there is a general increase in 1st ionisation energy as we go from Li to Ne and this is because the nuclear charge increases as you go across a period (more protons in the nucleus). However there will be a dip at Boron and Oxygen, they will have a lower actual 1st ionisation energy then we predict from the general increase. The dip at Boron is because the outermost electron is now in a p orbital instead of an s orbital as in beryllium, this p orbital is further from the nucleus than the s orbital so feels a lower nuclear charge meaning the electron is easier to remove. The second dip at oxygen is because the electrons in the px orbital are now paired, when two electrons share an orbital they repel each other so it is slightly easier to remove this electron.

Why do you think Be doesn’t show the same dip as oxygen even though it has two paired electrons in the s orbital?

You might find it helpful also to write out the electron configurations of the +1 ions produced from the ionisation.

Answered by Alexandra B. Chemistry tutor

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