What causes a chemical reaction to happen?

There are two aspects to this question: thermodynamics and kinetics.
It is a fundamental law that the entropy of the universe must increase for a process to be feasible. This implies that the Gibbs Free Energy Change ΔG must be negative for a reaction to be feasible. It is given by ΔG= ΔH-TΔS where ΔH and ΔS are the enthalpy and entropy changes of the system and T is the temperature. [Derivation beyond A Level but could do in tutorial if tutee was interested.]
However, for a reaction to be noticeable, it must have a fairly high rate. The rate depends on the temperature, the stability of transition states and intermediates, the strength of the reacting bonds, and the geometries of the molecules, among other factors. The rate constant for a reaction is given by the Arrhenius equation.

JL

Related Chemistry A Level answers

All answers ▸

A buffer solution is made with a pH of 5.000. Solid sodium ethanoate, CH3COONa, is added to 400 cm^3 of 0.200 mol dm^–3 ethanoic acid (Ka = 1.75 × 10^–5 mol dm^–3). Calculate the mass of sodium acetate that must be dissolved in the acid to prepare this


Draw the structure, name the shape and show bond angles of the molecules XeF4 and SbF4-. In your answer explain why each structure is different, despite both having a central atom, surrounded by 4 fluorine atoms.


Can you describe four variables which affect the rate of a chemical reaction and how they affect the rate?


How do you answer a long answer question on how buffer systems work?