Predict whether the lattice energy of magnesium oxide, MgO, is more or less exothermic than the lattice energy of magnesium sulfide, MgS. Justify your answer in terms of the sizes and the charges of the ions involved.

To start with, we can clearly see that the difference between MgO and MgS is the anions, we have O(2-) and S(2-). As we know (from looking at the periodic table) O(2-) has a smaller ionic radius, and thereby higher charge density than S(2-), as it has the same charge but packed into a smaller space. As a result, O(2-) will form stronger electrostatic attractions i.e. ionic bonds to Mg(2+) due to the smaller ionic radius and higher charge density, thereby MgO will have a more exothermic lattice enthalpy due to the stronger ionic bonds relative to MgS.

HA
Answered by Huzair A. Chemistry tutor

20213 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

What is an acid and what is the difference between and strong and weak acid


What product would you expect to obtain when reacting ethanal (or acetaldehyde) with potassium cyanide (KCN) in dilute acid? Draw a curly arrow mechanism for this transformation, and determine whether you obtain one enantiomer or a racemic mixture.


Explain why there is a general increase in the first ionisation energy across the third period.


0.04 moles of sulfur trioxide is placed in a flask (1.50dm^3) and allowed to reach equilibrium at 600 degrees. If 30% of the sulfur trioxide decomposes to sulfur dioxide and oxygen - what is the equilibrium constant?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning