Why is a nucleophilic substitution reaction between ammonia and benzene unlikely?

A nucleophilic substitution reaction is when a nucleophile (an electron pair donor) replaces an atom or part of a molecule. In this scenario ammonia (NH3) is the nucleophile as it contains a lone pair of electrons on the nitrogen atom and it is trying to replace something from benzene. However benzene contains a ring of delocalised electrons that exists either above or below the planar carbon ring. This is a region of high electron density that will repel other electrons. Hence ammonia cannot attack benzene as the lone pair of electrons in an ammonia molecule are repelled away by the ring of delocalised electrons. This makes a reaction between the two heavily unlikely and it also explains why benzene usually undergoes electrohilic substitution reactions as opposed to nucleophilic substitution as only a strong electrophile (electron pair acceptor) is capable of being attracted to the benzene ring.

AS
Answered by Archit S. Chemistry tutor

9420 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Why does ethanoyl chloride have a lower boiling point that pentanoyl chloride?


Describe the arrangement of protons, neutrons and electrons in an atom of Neon (Atomic No. 10, Atomic Weight 20.18). You may use diagrams to aid you.


How does pH relate to pKa?


State and explain the trend in ionisation energies and its effect on the reactivity of groups containing metals.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

© MyTutorWeb Ltd 2013–2025

Terms & Conditions|Privacy Policy
Cookie Preferences