Draw the structure of chlorine pentafluoride (ClF5) according to the VSEPR theory

The molecule is uncharged, so we can find that chlorine is in its +5 oxidation state. Since there are 5 Cl-F bonds, there are 5 bonding electron pairs around the central Cl atom. We also know that chlorine is in group 7, so it has 7 valence electrons. 5 out of those seven are "tied up" in the Cl-F bonds, thus the remaining two must form a non-bonding electron pair. We have 6 electron pairs (5 bonding and 1 non-bonding) to arrange around the chlorine center - which suggests an octahedral shape. However, since we have one electron pair, the shape of the molecule will be pyramidal.

PS
Answered by Peter S. Chemistry tutor

15239 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

explain why barium sulfate is used in barium meals despite being toxic


Explain why fluorine is reactive


Consider the transition metal complex [CoCl3(CO)3]. What is a) The oxidation state of the metal centre. b) The dn configuration of the metal centre. c) The co-ordination number of the metal centre.


Explain why the product of a nucleophilic addition to butanone does not effect plane polarized light.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning