How and why does sp3 hybridization occur?

1st consider the bonding in methane, CH4. The carbon atom forms 4 single covalent bonds to hydrogen atoms. However, when we consider the electronic configuration of Carbon (electrons-in-box notation), there are only 2 unpaired valence electrons, and hence there are only 2 available electrons for bonding. Hybridization is the process by which 4 electrons are made available for bonding.
Consider the energy profile diagram of the Carbon atom. The 1st step in hybridisation is the promotion of one electron from the filled 2s orbital to the empty 2pz orbital. Now all the 2s and 2p orbitals are singly occupied. The 2nd step is the rearrangement of these orbitals into 4 degenerate sp3 hybrid orbitals. The reason for hybridisation is found in comparing the energy released when 2 bonds are formed versus when 4 bonds are formed. Twice as much energy is capable of being released when Carbon is hybridised than when it is not. Therefore, Carbon is in a more stable and lower-energy state when hybridised. 

FD
Answered by Farah D. Chemistry tutor

14850 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Work out the shape of an SF6 molecule


An iron-alloy nail (2.41g) is dissolved in 100cm3 acid. 10cm3 portions of this solution are titrated with KMnO4 (0.02M) and 9.80cm3 of KMnO4 was needed to react with iron solution. What % of iron by mass is in the nail?


A sample of nitrogen gas is heated to 100°C, at a pressure of 10kPa and volume of 0.2m^3. How many moles of gas are present?


Q1. Two beakers, A and B, each contain 100.0 cm^3 of 0.0125 mol/dm^3 nitric acid. Calculate the pH of the solution formed after 50.0 cm^3 of distilled water are added to beaker A. Give your answer to 2 decimal places.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning