What is hydrogen bonding and why does water have a higher boiling point than methanol?

Hydrogen bonding is an intermolecular interaction between a partially positively charged hydrogen atom on one molecule and a partially negatively charged atom on another molecule. The difference in charge is due to the atom bonded to the hydrogen being more electronegative. Water has two partial positive hydrogens and one partial negatively charged oxygen whereas methanol only has one partial positive hydrogen (with the methyl group being unable to take part in hydrogen bonding). From this, a greater amount of hydrogen bonding can take place between water molecules than between methanol molecules. Thus a greater amount of thermal energy is needed to overcome these intermolecular forces for water, leading to its boiling point being higher than methanol.

MQ
Answered by Max Q. Chemistry tutor

28445 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Explain why the enthalpy of lattice dissociation of potassium oxide is less endothermic than that of sodium oxide. ( 2 Marks)


Which has a lower boiling point chlorine or bromine, and why?


Why does Benzene require a catalyst to react with Bromine whereas Phenol does not?


Explain how the electron pair repulsion theory can be used to deduce the shape of, and the bond angle in, NH3.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning