Benzene reacts with Chlorine gas in the presence of iron trichloride to yield hexachlorobenzene. However, when it reacts with fluorine gas, it forms a quinoid product (I would actually draw it for them - no need to know the name). Why the difference?

Fluorine is much more reactive than chlorine, even destroying the aromaticity. This is at the expense of the very strong C-F bonds (good orbital size and energy overlap) that are formed. C-Cl bonds are weaker so even when benzene is "burnt" in chlorine, the aromatic ring stays intact.

RB
Answered by Radu B. Chemistry tutor

2638 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Define the term 'first ionisation energy' and explain why the first ionisation energy shows a general increase across period 2


Explain what the rate-determining step in a reaction is with reference to activation energy.


What is a buffer, and how does it respond to the addition of acid or alkali?


Explain why silicon dioxide has a higher melting point than sulphur trioxide


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning