Benzene reacts with Chlorine gas in the presence of iron trichloride to yield hexachlorobenzene. However, when it reacts with fluorine gas, it forms a quinoid product (I would actually draw it for them - no need to know the name). Why the difference?

Fluorine is much more reactive than chlorine, even destroying the aromaticity. This is at the expense of the very strong C-F bonds (good orbital size and energy overlap) that are formed. C-Cl bonds are weaker so even when benzene is "burnt" in chlorine, the aromatic ring stays intact.

RB
Answered by Radu B. Chemistry tutor

2582 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

A buffer solution was formed by mixing 20.0 cm^3 of sodium hydroxide solution of concentration 0.100 mol dm^–3 with 25.0 cm^3 of ethanoic acid of concentration 0.150 mol dm^–3. CH3COOH + NaOH---CH3COONa + H2O Calculate the pH of this buffer solution.


The lattice enthalpies of calcium oxide and magnesium oxide are different. Comment on this difference.


Discuss the trend in first ionisation energies across the second period of the periodic table.


Explain why longer chain alkanes have a higher boiling point than shorter chains.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning