Why does propanol have a higher boiling point than propanone, propanal or methyl ethanoate?

Molecules of propanol have a hydrogen directly bonded to a NOF atom (oxygen in this case), which means that they can hydrogen bond with eachother. The oxygen in the other three molecules is only bonded to a carbon atom so hydrogen bonding is not possible. All the molecules have Van der Waals forces between them but propanol has the addition of having hydrogen bonding, which is slightly stronger. The stronger forces between molecules means that more energy is required to break apart the molecules and therefore the substance has a higher boiling point. Remember boiling point is the temperature that corresponds to the energy required to break the intermolecular forces of attraction.

Answered by Katharine W. Chemistry tutor

26589 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Can you explain the trend in ionisation energy across the periodic table?


A solution of acetic acid and sodium acetate was prepared, by dissolving 4.1 g of sodium acetate in 750 cm^3 of 0.085 mol/dm^3 acetic acid, at 25 degrees. 10 Cm^3 of 2 mol/dm^3 HCl was added. Ka is 1.76*10^-5, calculate and explain the change in pH


What is the difference between exothermic and endothermic?


What are the differences between sigma and pi bonds?


We're here to help

contact us iconContact usWhatsapp logoMessage us on Whatsapptelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

© MyTutorWeb Ltd 2013–2024

Terms & Conditions|Privacy Policy