BeCl2 has a linear shape with a bond angle of 180 degrees, where as H2O has a bent shape with a bond angle of 104.5 degrees. Explain why these molecules have different shapes despite having the same general formula of AB2.

BeCl2 contains 2 bonding pairs of electrons which arrange themselves as far away as possible to minimise the electron repulsion between them, giving a bond angle of 180 degrees and a linear shape. H2O also has 2 bonding pairs of electrons, but also 2 lone pairs of electrons on the oxygen atom. Therefore the 4 pairs of electrons spread themselves out as far as possible to minimise electron repulsion, however the repulsion between 2 lone pairs is greater than between a bonding pair and a lone pair, so the 2 lone pairs of electrons squish together the 2 bonding pairs further together, reducing the bond angle from the normal tetrahedral 109.5 degrees to 104.5 degrees , giving a bent shape.

SR
Answered by Sam R. Chemistry tutor

35242 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Write an expression and units for equilibrium constant for this reaction: 2SO2(g)+O2(g)<-->2SO3(g)


Explain how chromatography is used to separate components in a mixture.


Explain how pH changes can be minimised using a mixture of a weak acid and it's conjugate base


What is the optical activity of the product formed when propanone is refluxed with HCN with KCN dissolved in ethanol and why?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning