Describe and explain the trend in boiling points in the first four hydrogen halides

HF has the highest boiling point this is followed by HI, then HBr with HCl having the lowest boiling point of the four molecules. This is because HF is able to form Hydrogen bonds whereas the other three molecules are unable to do so because their electronegativity is not large enough to create a sufficient dipole. The boiling point then increases down the group from HCl to HI because the halogens increase in size. This means that the van der waal forces are stronger down the group therefore they require more energy to overcome. The more energy that is required to overcome the intermolecular forces the higher the boiling point.

TM
Answered by Theo M. Chemistry tutor

44473 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

I am struggling to with unseen organic chemistry mechanism. I don’t know where to begin drawing them.


Lead (IV) oxide reacts with concentrated hydrochloric acid as follows: PbO2(s) + 4HCl(aq) -----> PbCl2(s) + Cl2(g) + 2H2O(l) What mass of lead chloride would be obtained from 37.2g of PbO2, and what mass of chlorine gas would be produced


What affects the boiling point of an alkane and why?


How do you decide what the sign of the enthalpy change should be?


We're here to help

contact us iconContact usWhatsapp logoMessage us on Whatsapptelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

© MyTutorWeb Ltd 2013–2025

Terms & Conditions|Privacy Policy
Cookie Preferences