The ratio between the molar mass of an alkene(A) and an alkyne(B) with the same number of carbon atoms is 1.05. Find the molecular formulas of the two hydrocarbons then write the reaction for how we can obtain the alkene A from the alkyne B.

We start by remembering the general formulas of alkenes and alkynes:
Alkenes - CnH2n
Alkynes - CnH2n-2
We calculate the molar mass of both of these using the fact that the atomic mass of carbon is 12 and for hydrogen 1 :
 μA=12n+2n=14n grams/mole
 μB=12n+2n-2=14n-2 grams/mole
The ratio then becomes:
μ/ μB=1.05
14n / 14n - 2 = 1.05
14n =(14n - 2) * 1.05
14n = 14.7n - 2.1
14.7n - 14 = 2.1
0.7n = 2.1
n = 3
Therefore, our hydrocarbons are:
A = C3H6 - propene  
B = C3H4 - propyne
The reaction to obtain propene from the propyne is:
CH≡C-CH3 + H2 --Ni---> CH2=CH-CH3
The reaction is a hydrogenation one and the condition needed for it Nickel.

CB

Related Chemistry A Level answers

All answers ▸

Describe the products of the following Friedl-Crafts substitution and explain the role of the AlCl3 in the reaction: C6H6 + CH3C(O)Cl + AlCl3 = ?


Explain why the second ionisation energy of Magnesium is lower than the second ionisation energy of Sodium.


Explain why Magnesium has a greater second ionisation energy than strontium


Which Ion from Na+ and Mg2+ has a smaller atomic radii? Explain why?