Explain the trend in first ionisation energy along period 3

Going across a period there is generally an increase in first ionisation energy. This is because there are more protons in each nucleus leading to a greater positive charge and stronger electrostatic force of attraction between the nucleus and outer electron. Each successive electron enters the same shell so there is no increase in shielding.The two exceptions to the trend are aluminium and and sulphur. For aluminium IE is lower because the electron enters 3p rather than 3s so less energy is required to remove it. For sulphur IE falls because it is 3p4, this means there are two electrons in one p orbital. As a result, IE will be lower as electron repulsion means that the force of attraction between the electron and nucleus is reduced which makes it easier to remove.

JD
Answered by Jasmine D. Chemistry tutor

2973 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Explain the delocalised model of benzene, and hence why it is less reactive with electrophiles than cyclohexene


Explain the trend in melting points of the period 3 elements


describe the structure of graphite


How does the 3D dash and wedge notation work?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning