Why does calcium nitrate decompose in a similar way to magnesium nitrate, but require a higher temperature for decomposition?

Calcium ions (Ca2+) have the same charge as magnesium ions (Mg2+) but Ca2+ ions have a larger ionic radius (as ionic radius increases down the group). This means Ca2+ has a lower charge density than Mg2+. With a lower charge density, Ca2+ ions cause less polarisation and distortion of the nitrate (NO3-) electron cloud (and N-O/N=O bonds) than Mg2+ions making decomposition harder. Therefore, calcium nitrate requires more heat to be decomposed.

KA

Related Chemistry A Level answers

All answers ▸

How do you describe the process of recrystallisation to purify a product?


There are two methods of ionisation in a time of flight spectrometer, name and explain one of these methods in detail.


Why are transition metal complexes coloured?


Briefly describe the nature of three types of intramolecular bonding and two types of intermolecular bonding (drawings encouraged)