Why does the nucleophilic addition of a cyanide ion to an aldehyde form a racemic mixture?

Because the plane of the C=O bond in an aldehyde is flat, and so the nucleophilic attack of CN- onto the C can occur above or below the plane of the molecule, producing two different stereoisomers of a 2-hydroxyalkane molecule with 50/50 split (as both structures are equally thermodynamically favourable). This produces a racemic mixture

SA

Related Chemistry A Level answers

All answers ▸

explain why the electronegativity of fluorine is greater than that chlorine


X, a gas, has a mass of 0.270g and is present in a gas syringe with a volume of 105.0cm^3 at 97C and 100kPa. Calculate the Mr of X. (5 marks)


Draw a mechanism for electrophilic addition?


Describe how a buffer solution based on hydrochloric acid can act as a buffer. (5)