Imagine a reaction A for which the values of ΔH and ΔS are both negative. It is known that the absolute value of ΔS is 3 times smaller than the absolute value of ΔH. For what values of T does reaction A occur spontaneously?

We know that a reaction occurs spontaneously when ΔG<0 and that ΔG=ΔH-TΔS. So, we know that the reaction will be spontaneous when ΔH<TΔS.Its is given that ΔH and ΔS are <0 and that |ΔH|=3*|S|. From this we can conclude that the inequation ΔH<TΔS will be true whenT< 3K. We also have to keep in mind that the temperature can never be lower than the absolute zero (0K) and so, the answer is 0K < T < 3K.

AC

Related Chemistry A Level answers

All answers ▸

Explain: 1. Why butanoic acid has a higher boiling point than butan1-ol? 2. Why carboxylic acids of short chain length are more soluble in water than those with longer carbon chain length?


How does aromatic electrophilic substitution work?


3-methyl pent 2 ene reacts with HBr to form two products. Which of these products is the minor and major product and why?


State and explain the general trend in first ionisation energy across Period 3