What reaction occurs when benzene is mixed with equal amounts of sulphuric and nitric acid?

Intro:This is an electrophilic substitution reaction (nitration)Nitric acid and sulphuric acid are used to create the electrophile (NO2+)The electrophile then substitutes itself with a H atom on the benzene ring
Formation of the electrophile:Nitric acid is weaker than sulphuric acid, therefore it acts as a base in the reactionH2SO4 + HNO3 = H2NO3+ + HSO4-H2NO3+ = H2O + NO2+NO2+ is the electrophile - it attacks the delocalised ring of electrons in benzene[demonstrate mechanism of electrophile formation]
The Reaction:C6H6 + H2SO4 + HNO3 = C6H5NO2 + H2O + H2SO4The sulphuric acid is a catalyst, therefore it is re-formed[demonstrate mechanism of main reaction]

SS

Related Chemistry A Level answers

All answers ▸

Relationship between moles and Avogadro's constant


Discuss the reactivity benzene, chlorobenzene, toluene and phenol in electrophillic aromatic substitution


What type of reaction do haloalkanes undergo with nucleophiles?


Calculate the mass of the following substance: a) 2.5 x 10^23 molecules of N2