What is the effect of temperature on K(equilibrium constant)?

For this question we need to consider the equation:

ΔStotal = ΔSsystem - ΔH/T

For and exothermic reaction, -ΔH/T is positive. Therefore, as T increases -ΔH/T becomes more negative, ΔStotal becomes less positive/more negative and the position of equilibria moves to the left. This results in K decreasing.

 

For an endothermic reaction, -ΔH/T is negative. Therefore, as T increases, -ΔH/T becomes less negative, ΔStotal becomes less negative/more positive and the position of equilibrium moves to the right. This results in K increasing. 

 

 

OP
Answered by Olivia P. Chemistry tutor

8507 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Propane and Chlorine react in the presence of UV light to give 2-chloropropane and HCl. Estimate the enthalpy change of this reaction using the following bond enthaplies (KJ/mol) : C-H=+413, Cl-Cl=+243, C-Cl=+346 and H-Cl=+432.


Thermodynamics with a focus on entropy


What are the differences between sigma and pi bonds?


What is Gibbs Free Energy?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning