In fractional distillation the shorter hydrocarbons have lower boiling points and distil off first. Why?

Boiling points are determined by the interactions between the individual hydrocarbon molecules. The weaker the interactions, the less energy is required to boil the hydrocarbon and the lower the boiling point. Shorter hydrocarbons have weaker interactions whereas longer hydrocarbons have stronger interactions between each other. As a result they have different boiling points and can be separated by fractional distillation.

HB

Related Chemistry GCSE answers

All answers ▸

Explain why graphite can conduct electricity.


How do you test for alkenes and alkanes?


Describe the structure and bonding in Graphite?


What is an acid?