Why do ionic compounds conduct electricity when molten or in solution, but not when solid?

Substances can conduct electricity if there is a way for charge to flow through that substance. For a substance to conduct electricity, it needs to contain some sort of charge carrier - this could be an electron or an ion - that is free to move within the substance.
When an ionic substance is molten or dissolved, the ions that make it up are free to move within the substance and carry charge through it, i.e. conduct electricity. However when an ionic compound is solid, it exists as a giant ionic lattice, where positively charged cations and negatively charged anions are held in a lattice by strong ionic bonds and are not free to move around. This means there is no possible movement of charge, so a solid ionic compound cannot conduct electricity.

JQ
Answered by James Q. Chemistry tutor

84572 Views

See similar Chemistry GCSE tutors

Related Chemistry GCSE answers

All answers ▸

In a titration, 45.0 cm^(3) of 0.100 mol dm^(-3) sodium hydroxide solution is exactly neutralised by 40.0 cm^(3) of a dilute hydrochloric acid solution. Calculate the concentration of the hydrochloric acid solution in mol dm^(-3).


Potassium forms an ionic compound with sulfur. Describe what happens when two atoms of potassium react with one atom of sulfur. Give your answer in terms of electron transfer. Give the formulae of the ions formed. (5 marks)


What is an ionic bond?


Which factors should be altered in chemical reaction between zinc (s) and hydrochloric acid (l) in order to speed up the rate of reaction?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning