What is hydrogen bonding and why does water have a higher boiling point than methanol?

Hydrogen bonding is an intermolecular interaction between a partially positively charged hydrogen atom on one molecule and a partially negatively charged atom on another molecule. The difference in charge is due to the atom bonded to the hydrogen being more electronegative. Water has two partial positive hydrogens and one partial negatively charged oxygen whereas methanol only has one partial positive hydrogen (with the methyl group being unable to take part in hydrogen bonding). From this, a greater amount of hydrogen bonding can take place between water molecules than between methanol molecules. Thus a greater amount of thermal energy is needed to overcome these intermolecular forces for water, leading to its boiling point being higher than methanol.

MQ
Answered by Max Q. Chemistry tutor

22699 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

What are electrophilic addition reactions of alkenes?


Calculate the pH of the solution formed when 30 cm3 of 0.150 moldm-3 aqueous sulfuric acid is added to 30 cm3 of 0.200 moldm-3 aqueous potassium hydroxide at 25 C.


Why does propanol have a higher boiling point than propanone, propanal or methyl ethanoate?


Why can both major and minor products be formed during an eimination reaction?


We're here to help

contact us iconContact usWhatsapp logoMessage us on Whatsapptelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

© MyTutorWeb Ltd 2013–2025

Terms & Conditions|Privacy Policy
Cookie Preferences