What is hydrogen bonding and why does water have a higher boiling point than methanol?

Hydrogen bonding is an intermolecular interaction between a partially positively charged hydrogen atom on one molecule and a partially negatively charged atom on another molecule. The difference in charge is due to the atom bonded to the hydrogen being more electronegative. Water has two partial positive hydrogens and one partial negatively charged oxygen whereas methanol only has one partial positive hydrogen (with the methyl group being unable to take part in hydrogen bonding). From this, a greater amount of hydrogen bonding can take place between water molecules than between methanol molecules. Thus a greater amount of thermal energy is needed to overcome these intermolecular forces for water, leading to its boiling point being higher than methanol.

MQ
Answered by Max Q. Chemistry tutor

27654 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Why does ionisation energy decrease down group 2?


Explain how a coordinate bond forms


How can pressure affect the equilibrium shift of a reversible gaseous reaction?


A naturally occurring sample of the element boron has a relative atomic mass of 10.8 In this sample, boron exists as two isotopes. Calculate the percentage abundance of 10B in this naturally occurring sample of boron.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning