Why, in the bromination of phenols, do you not need an acid catalyst like you do in the bromination of benzene?

Benzene's delocalised π electrons means that it is not very nucleophilic and so cannot polarise a neutral molecule and produce the required electrophile. As a result it require a catalyst to form the electrophile. In phenols, the lone pair from the oxygen delocalises into the π electrons, increasing the electron density in the ring and making it more nucleophilic. This means that it is more able to polarise a molecule and produce an electrophile meaning that a catalyst isn't required.

SA
Answered by Sian A. Chemistry tutor

7538 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Why is the Mg2+ ion smaller in radius than the Na+ ion?


What is a radical?


What are the different types of bonding in chemicals?


Name the type of reaction and outline the mechanism for the reaction of the alcohol (CH3)2CHOH with the acyl chloride CH3COCl. Explain which orbitals take part in the reaction.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning