Why, in the bromination of phenols, do you not need an acid catalyst like you do in the bromination of benzene?

Benzene's delocalised π electrons means that it is not very nucleophilic and so cannot polarise a neutral molecule and produce the required electrophile. As a result it require a catalyst to form the electrophile. In phenols, the lone pair from the oxygen delocalises into the π electrons, increasing the electron density in the ring and making it more nucleophilic. This means that it is more able to polarise a molecule and produce an electrophile meaning that a catalyst isn't required.

SA
Answered by Sian A. Chemistry tutor

7263 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Explain the position and numbering system of elements on the periodic table.


There are two methods of ionisation in a time of flight spectrometer, name and explain one of these methods in detail.


By considering the mechanism of the two step reaction of butanone and NaBH4 followed by dilute acid, explain why the product has no effect on plane polarised light.


Aminoethane can be prepared by a reduction reaction. Identify a starting compound that can be used to prepare aminoethane by reduction, give the necessary reagent and write an equation for the reaction.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning