Why, in the bromination of phenols, do you not need an acid catalyst like you do in the bromination of benzene?

Benzene's delocalised π electrons means that it is not very nucleophilic and so cannot polarise a neutral molecule and produce the required electrophile. As a result it require a catalyst to form the electrophile. In phenols, the lone pair from the oxygen delocalises into the π electrons, increasing the electron density in the ring and making it more nucleophilic. This means that it is more able to polarise a molecule and produce an electrophile meaning that a catalyst isn't required.

SA
Answered by Sian A. Chemistry tutor

7567 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Explain why alkenes can have stereoisomers


An unknown gas from a reaction is contained in a 2 litre beaker, at standard atmospheric pressure and a Temperature of 25 Celsius. Calculate the number of moles of the gas.


Explain what is meant by the term 'buffer solution' and give an example of a biological buffer system.


Explain in detail what do you understand by catalyst, what makes them so useful and give two example of catalytic processes including the name catalyst used.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning