Why, in the bromination of phenols, do you not need an acid catalyst like you do in the bromination of benzene?

Benzene's delocalised π electrons means that it is not very nucleophilic and so cannot polarise a neutral molecule and produce the required electrophile. As a result it require a catalyst to form the electrophile. In phenols, the lone pair from the oxygen delocalises into the π electrons, increasing the electron density in the ring and making it more nucleophilic. This means that it is more able to polarise a molecule and produce an electrophile meaning that a catalyst isn't required.

SA
Answered by Sian A. Chemistry tutor

8058 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

What is electronegativity?


Write a half-equation for the overall oxidation of ethanol into ethanoic acid.


Describe, in three steps, how you would synthesise phenylethylamine (C6H5CH2CH2NH2) from methylbenzene, giving reagents and conditions for each step. For each step, state the type of reaction that occurs.


Describe the structure of benzene, and how this affects its stability.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning