What is meant by the term optical isomerism?

Optical isomerism is a form of stereoisomerism (different arrangement of the same atoms in 3D space) which is caused by the presence of a chiral carbon in a molecule. A chiral carbon is a carbon with four different groups attached to it, for example a carbon bonded to a hydrogen atom, carboxylic acid group, amino group and a methyl group is a chiral carbon. The optical isomers of a chiral molecule are known as enantiomers and these enantiomers are non super-imposable mirror images of each other. Enantiomers will rotate plane-polarised light in opposite directions but by an equal amount, so when equal numbers of enantiomers are present in a mixture (known as a racemic mixture), no rotation of plane-polarised light is observed.

SM
Answered by Sophie M. Chemistry tutor

2422 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

Describe the structure and bonding in Benzene (C6H6).


State and explain the conditions for cis/trans isomerism and how this differs from E/Z isomerism.


Phosphorus(III) chloride molecules are pyramidal with a bond angle less than 109.5°. Explain why a phosphorus(III) chloride molecule has this shape and bond angle.


The boiling point of the halogen elements increase down the group from chlorine to bromine to iodine. Please explain this trend for 3 marks.


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning