Explain the 3 pieces of evidence that disprove Kekule's model of benzene.

Kekulé's model of benzene is that it has 3 double bonds, in a ring of 6 carbons.
One - Benzene isn't very reactive, so if Kekulé's model were to be correct, there would be 3 double bonds in benzene, and so it would react with bromine and decolourise it. It also doesn't do electrophilic addition.Two - The bond lengths in benzene are all the same length. If Kekulé's model was correct, there would be 2 different bond lengths, corresponding to the double bonds and the single bonds in the ring. The actual bond length is between the single and double bond length of carbon.Three - the hydrogenation enthalpy of benzene is expected to be three times that of cyclohexene, if it were Kekulé's model. However, it is smaller, and less energy is produced than expected, meaning that the actual model of benzene is a lot more stable than Kekulé's model.
The correct model for benzene is the delocalised model.

EW
Answered by Ellie W. Chemistry tutor

34723 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

What factors affect ionisation energy and how does each of them affect it?


How does hydrogen bonding work?


The boiling points of ammonia (NH3), fluorine (F2) and bromine (Br2) are -33, -188 and +59 degrees celsius respectively. Explain the differences in these boiling points, including the names of any relevant forces and particles.


Which of Na+ and Mg2+ is the smaller ion. Explain your answer. (2 marks)


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2026 by IXL Learning