Explain why transition metal compounds are often coloured in solution.

The valence electrons of transition metals are found in d-orbitals. When the metal ion forms a complex with ligands the d-orbitals split into two different energy levels, and the gap between these levels happens to correspond with that of visible light.

This means that when the electrons in the lower level are promoted to the higher level part of the visible spectrum is absorbed - leading to the reflected light being coloured.

PD

Related Chemistry A Level answers

All answers ▸

What is the meaning of the term 'structural isomers'?


What is the difference between complete and incomplete combustion of a hydrocarbon?


A 1000 cm3 container of ammonia (NH3) has a mass of 20.7g, it is stored at room temperature (298 K). When empty the container has a mass of 20.0 g, calculate the pressure inside the container in kPa to an appropriate number of significant figures.


Write the electronic configuration of the following using the orbital method: 4. N3- 5. Ar 6. Sc3+ 7. Mn2+ 8. Fe3+ 9. V3+