Why is phenylamine a weaker base than ethylamine?

Phenylamine is a weaker base than ethylamine because the lone pair on the nitrogen atom in phenylamine is spread into the delocalised electron ring in benzene, therefore is less available for protonation than in ethylamine. This reduced availability causes the phenylamine to be a weaker base.

AJ

Related Chemistry A Level answers

All answers ▸

Q3. A third beaker, C, contains 100.0 cm^3 of 0.0125 mol/dm^3 ethanoic acid ( Ka = 1.74 × 10^−5 mol/dm^3 at 25 ºC). Write an expression for Ka and use it to calculate the pH of the ethanoic acid solution in beaker C.


Explain why benzene requires use of a halogen carrier catalyst to react with bromine while phenol does not.


Describe the changes in equilibrium of ethanol production from ethene and water (enthalpy of reaction is ∆H = - 46 kJ/mol) when: (a) a high pressure is applied; (b) ethanol concentration is increased; (c) temperature is increased; (d) a catalyst is used.


How might you distinguish between a primary and secondary alcohol?