Explain why the boiling point of PH3 is lower than the boiling point of AsH3

AsH3 is a larger molecule than PH3 as As is lower down the periodic table, so has a higher atomic number so more electrons. Therefore AsH3 has more electrons than PH3 meaning that the instantaneous dipole produced by AsH3 is greater. Therefore the induced dipoles on neighbouring molecules are greater, so the London forces are stronger than in PH3. Therefore more energy is required to overcome the intermolecular forces between the molecules.

FO
Answered by Freya O. Chemistry tutor

27598 Views

See similar Chemistry A Level tutors

Related Chemistry A Level answers

All answers ▸

What is a racemic mixture and why is it not optically active?


How does a acid buffer work?


Draw the mechanism for the reaction of an acid chloride with an alcohol to form an ester


What is the definition of a H-Bond?


We're here to help

contact us iconContact ustelephone icon+44 (0) 203 773 6020
Facebook logoInstagram logoLinkedIn logo

MyTutor is part of the IXL family of brands:

© 2025 by IXL Learning